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Making a solar cell from your kitchen

Written by Paulo Martirez on Thursday, June 07, 2007


A solar cell is a device for converting energy from the sun into electricity.

Our solar cell is made from cuprous oxide instead of silicon. Cuprous oxide is one of the first materials known to display the photoelectric effect, in which light causes electricity to flow in a material.

Materials Needed:

• 1/2 square foot sheet of copper flashing from the hardware store.
• 2 alligator clip leads.
• A sensitive micro-ammeter that can read currents between 10 and 50 microamperes.
• An electric stove.
• 1 large clear plastic bottle off of which you can cut the top.
• 2 tbsp Table salt.
• Tap water.
• Sand paper or a wire brush on an electric drill.
• Sheet metal shears for cutting the copper sheet.

Building Instructions:

1. The first step is to cut a piece of the copper sheeting that is about the size of the burner on the stove. Wash your hands so they don't have any grease or oil on them. Then wash the copper sheet with soap or cleanser to get any oil or grease off of it. Use the sandpaper or wire brush to thoroughly clean the copper sheeting, so that any sulphide or other light corrosion is removed.

2. Next, place the cleaned and dried copper sheet on the burner and turn the burner to its highest setting.

As the copper starts to heat up, you will see beautiful oxidation patterns begin to form. Oranges, purples, and reds will cover the copper.

As the copper gets hotter, the colors are replaced with a black coating of cupric oxide. This is not the oxide we want, but it will flake off later, showing the reds, oranges, pinks, and purples of the cuprous oxide layer underneath.

The last bits of color disappear as the burner starts to glow red.

3. When the burner is glowing red-hot, the sheet of copper will be coated with a black cupric oxide coat. Let it cook for a half an hour, so the black coating will be thick. This is important, since a thick coating will flake off nicely, while a thin coat will stay stuck to the copper.

4. After the half hour of cooking, turn off the burner. Leave the hot copper on the burner to cool slowly. If you cool it too quickly, the black oxide will stay stuck to the copper.

As the copper cools, it shrinks. The black cupric oxide also shrinks. But they shrink at different rates, which makes the black cupric oxide flake off.

The little black flakes pop off the copper with enough force to make them fly a few inches. This means a little more cleaning effort around the stove, but it is fun to watch.

5. When the copper has cooled to room temperature (this takes about 20 minutes), most of the black oxide will be gone. A light scrubbing with your hands under running water will remove most of the small bits. Resist the temptation to remove all of the black spots by hard scrubbing or by flexing the soft copper. This might damage the delicate red cuprous oxide layer we need to make to solar cell work.

6. Cut another sheet of copper about the same size as the first one. Bend both pieces gently, so they will fit into the plastic bottle or jar without touching one another. The cuprous oxide coating that was facing up on the burner is usually the best side to face outwards in the jar, because it has the smoothest, cleanest surface.

7. Attach the two alligator clip leads, one to the new copper plate, and one to the cuprous oxide coated plate. Connect the lead from the clean copper plate to the positive terminal of the meter. Connect the lead from the cuprous oxide plate to the negative terminal of the meter.

8. Now mix a couple tablespoons of salt into some hot tap water. Stir the saltwater until all the salt is dissolved. Then carefully pour the saltwater into the jar, being careful not to get the clip leads wet. The saltwater should not completely cover the plates -- you should leave about an inch of plate above the water, so you can move the solar cell around without getting the clip leads wet.

The solar cell is a battery, even in the dark, and will usually show a few microamps of current.

NOTE: The cell produces 50 microamps at 0.25 volts. This is 0.0000125 watts (12.5 microwatts). Don't expect to light light bulbs or charge batteries with this device. It can be used as a light detector or light meter, but it would take acres of them to power your house.

The 0.0000125 watts (12.5 microwatts) is for a 0.01 square meter cell, or 1.25 milliwatts per square meter. To light a 100 watt light bulb, it would take 80 square meters of cuprous oxide for the sunlit side, and 80 square meters of copper for the dark electrode. To run a 1,000 watt stove, you would need 800 square meters of cuprous oxide, and another 800 square meters of plain copper, or 1,600 square meters all together. If this were to form the roof of a home, each home would be 30 meters long and 30 meters wide, assuming all they needed electricity for was one stove.

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